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Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2

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dc.contributor.advisorMerchán Arenas, Diego Rolando
dc.contributor.authorMurcia Patiño, Andrés Felipe
dc.date.accessioned2019-05-11T01:26:28Z
dc.date.available2019-05-11T01:26:28Z
dc.date.issued2019-05-09
dc.descriptionEn este trabajo se tomó una muestra de poliestireno expandido (EPS) de una matriz de residuos sólidos, este material se utilizó como materia prima para la síntesis de poliamino estireno (PSNH2) en un proceso de dos pasos. Primero, se llevó a cabo la nitración de PS para obtener polinitro estireno (PSNO2) con un rendimiento de 10.18 % en función de grupos NO2 obtenidos. Seguidamente, el PSNO2 se redujo utilizando HCl/Sn, con un rendimiento del 50 % en función de grupos NO2 reducidos del precursor. La materia prima, el precursor y el producto final obtenido se caracterizaron mediante técnicas analíticas como IR, 1H-RMN, SEM-EDS y TGA. Con el material en nuestras manos, se evaluó su actividad de captura de CO2, obteniendo una capacidad de adsorción de 1.05 mmol g-1 de PSNH2.spa
dc.description.abstractA sample of expanded polystyrene (EPS) was isolated from a whole solid waste sample as raw material, for the synthesis of the polyamino styrene (PSNH2) in a two steps process. Initially, it was carried out the nitration of PS to obtain polynitro styrene (PSNO2) in a 10.18 % of yield according to the NO2 groups obtained. Afterwards, PSNO2 was reduced using HCl/Sn conditions, to obtain the PSNH2 in 50 % yield according to the reduction of NO2 groups of the precursor. Raw material, intermediary and the final product were completely characterized by chemical analytical techniques. With the new material in hands, it was used as solid support to CO2 capture, showing an adsorption capacity of 1.05 mmol g-1 of PSNH2.spa
dc.description.degreelevelMaestríaspa
dc.description.degreenameMagister en Ciencias y Tecnologías Ambientalesspa
dc.description.domainhttps://www.ustabuca.edu.co/spa
dc.format.mimetypeapplication/pdf
dc.identifier.citationMurcia Patiño, A. F. (2019). Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2 [Tesis de Maestría]. Universidad Santo Tomás, Bucaramanga, Colombiaspa
dc.identifier.instnameinstname:Universidad Santo Tomásspa
dc.identifier.reponamereponame:Repositorio Institucional Universidad Santo Tomásspa
dc.identifier.repourlrepourl:https://repository.usta.edu.cospa
dc.identifier.urihttp://hdl.handle.net/11634/16630
dc.language.isospa
dc.publisherUniversidad Santo Tomásspa
dc.publisher.branchCRAI-USTA Bucaramangaspa
dc.publisher.facultyFacultad de Química Ambientalspa
dc.publisher.programMaestría Ciencias y Tecnologías Ambientalesspa
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dc.rightsAtribución-NoComercial-SinDerivadas 2.5 Colombia
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.rights.coarhttp://purl.org/coar/access_right/c_abf2
dc.rights.localAbierto (Texto Completo)spa
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.5/co/
dc.subject.keywordCO2 capturespa
dc.subject.keywordExpanded polystyrenespa
dc.subject.keywordNitrationspa
dc.subject.keywordPolyamine styrenespa
dc.subject.keywordReduction of NO2spa
dc.subject.keywordUrban solid wastespa
dc.subject.lembPoliestirenospa
dc.subject.lembConversión de residuosspa
dc.subject.lembNitraciónspa
dc.subject.proposalCaptura de CO2spa
dc.subject.proposalNitraciónspa
dc.subject.proposalPoliestireno expandidospa
dc.subject.proposalPoliamino estirenospa
dc.subject.proposalReducción de grupos NO2spa
dc.subject.proposalResiduos sólidos urbanosspa
dc.titleSíntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2spa
dc.typemaster thesis
dc.type.categoryFormación de Recurso Humano para la Ctel: Trabajo de grado de Maestríaspa
dc.type.coarhttp://purl.org/coar/resource_type/c_bdcc
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.driveinfo:eu-repo/semantics/masterThesis
dc.type.localTesis de maestríaspa
dc.type.versioninfo:eu-repo/semantics/acceptedVersion

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