Synthesis and X-ray diffraction data of 1-N-(3-pyridylmethyl) aminonaphthalene hydrochloride

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dc.contributor.authorMorantes, L.R.spa
dc.contributor.authorMedina, C.F.spa
dc.contributor.authorHenao, J.A.spa
dc.contributor.authorKouznetsov, V.V.spa
dc.contributor.authorCamargo, H.A.spa
dc.coverage.campusCRAI-USTA Bogotáspa
dc.date.accessioned2020-01-17T15:13:53Zspa
dc.date.available2020-01-17T15:13:53Zspa
dc.date.issued2014-06spa
dc.description.abstractThe title compound 1-N-(3-pyridylmethyl)aminonaphthalene hydrochloride (C16H15N2Cl) was obtained by a reaction of α-naphthylamine (1) and N-pyridincarboxaldehyde (2) in anhydrous ethanol in the first step. The formed imine (3) was reduced with sodium borohydride in anhydrous methanol to give the product 1-N-(3-pyridylmethyl)aminonaphthalene (4). Finally, the hydrochloride was prepared by addition of a hydrochloric acid–ethyl acetate solution (ratio 1:3) with constant stirring and maintaining the temperature between 0 and 5 °C, obtaining a yellow polycrystalline solid corresponding to the respective derivative (5). The X-ray powder diffraction pattern for the new compound (5) was obtained. The compound (5) crystallizes in a monoclinic system with the space group P21/m (No. 11) and refined unit-cell parameters: a = 16.257 (8) Å, b = 9.236 (7) Å, c = 13.221 (6) Å, β = 94.87° (5), Z = 6, and V = 1978 (1) Å3.spa
dc.description.domainhttp://unidadinvestigacion.usta.edu.cospa
dc.format.mimetypeapplication/pdfspa
dc.identifier.doihttps://doi.org/10.1017/S0885715614000049spa
dc.identifier.urihttp://hdl.handle.net/11634/20692
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dc.rightsAtribución-NoComercial-CompartirIgual 2.5 Colombia*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/2.5/co/*
dc.subject.keywordDerivatizationspa
dc.subject.keywordX-ray powder diffractionspa
dc.subject.keyword1-naphthalene ammonium saltspa
dc.titleSynthesis and X-ray diffraction data of 1-N-(3-pyridylmethyl) aminonaphthalene hydrochloridespa
dc.type.categoryGeneración de Nuevo Conocimiento: Artículos publicados en revistas especializadas - Electrónicosspa

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