FORMULACIÓN DE UNA MEMBRANA POLIMÉRICA ELECTROHILADA PARA EL ESTUDIO DE ADSORCIÓN DE HIERRO Y CROMO EN AGUAS RESIDUALES PRODUCTO DE LA MINERÍA EN EL MUNICIPIO SAMACÁ Y CHIVATÁ, BOYACÁ

Vista sencilla de ítem
dc.contributor.advisorRodríguez Mesa, Mónica Helena
dc.contributor.advisorSegura Peña, Sully
dc.contributor.authorACEVEDO DURÁN, PAULA VALENTINA
dc.contributor.authorARIAS SOLER, STIVEN HERNANDO
dc.contributor.authorSEGURA PEÑA, SULLY
dc.contributor.authorSANCHEZ CEPEDA, ANGELA PATRICIA
dc.contributor.authorSALDAÑA, ADRIANA
dc.contributor.corporatenameUniversidad Santo Tomas
dc.date.accessioned2025-09-12T12:56:57Z
dc.date.available2025-09-12T12:56:57Z
dc.date.issued2025-09-10
dc.descriptionEl municipio de Samacá (Boyacá) constituye una importante zona en la extracción de carbón y producción de coque en Colombia. Un estudio realizado por la Universidad Santo Tomás Tunja, mediante un sistema de monitoreo continuo, ha identificado durante un periodo anual la presencia de concentraciones elevadas de metales pesados (arsénico, aluminio, hierro y cadmio) en aguas residuales de la región. Las concentraciones encontradas superan los limiten máximos permisibles establecidos por la Resolución 2115 de 2007, lo que representa un riesgo ambiental y sanitario considerable. Esta investigación propone el desarrollo de membranas filtrantes de alto rendimiento fabricadas mediante la técnica de electrohilado, utilizando una matriz compuesta de PVDF/PLA funcionalizada con oxido de grafeno. La integración de la nanopartícula de óxido de grafeno en la estructura polimérica confiere propiedades fisicoquímicas superiores, incluyendo una arquitectura microporosa optimizada y una distribución homogénea de grupos funcionales oxigenados con alta afinidad hacia iones metálicos. La membrana diseñada presenta características estructurales optimizadas (alta porosidad, superficie especifica elevada y distribución uniforme de sitios de adsorción) que facilitan la interacción entre los grupos funcionales oxigenados del OG y los cationes férricos, mediante mecanismos de adsorción superficial.
dc.description.abstractThis research proposes an alternative for water filtration through the design of a polymeric membrane elaborated with the electrospinning technique and using polymers polyvinylidene fluoride (PVDF) and poly (lactic acid) (PLA) functionalized with graphene oxide (GO) to adsorb iron cations. It is expected to obtain a polymeric membrane with high porosity, contact surface area and electrostatic interaction between the oxygenated functional groups of the OG and the metal ion, properties that allow obtaining a high percentage of iron adsorption. This proposal arises from the need to decontaminate industrial wastewater, which has a negative impact on the environment. The municipality of Samacá (Boyacá) is an important coal and coke production area. A study carried out by the Universidad Santo Tomás Tunja through a community platform for monitoring water quality in this region reported for one consecutive year the presence of heavy metals such as arsenic, aluminum, iron and cadmium in wastewater. The amounts reported are higher than the permissible limit according to Resolution 2115 of 2007. Thus, this alternative is proposed as a solution to this local problem, starting with the study of this ion.
dc.description.degreelevelMaestríaspa
dc.description.degreenameMagíster en Ingeniería Civil con Énfasis en Hidroambientalspa
dc.format.mimetypeapplication/pdf
dc.identifier.citationAcevedo Durán, P. V., & Arias Soler, S. H. (2025). Formulación de una membrana polimérica electrohilada para el estudio de adsorción de hierro y cromo en aguas residuales producto de la minería en el municipio Samacá y Chivatá, Boyacá [Tesis de maestría, Universidad Santo Tomás, Sede Tunja]. Universidad Santo Tomás.
dc.identifier.instnameinstname:Universidad Santo Tomásspa
dc.identifier.reponamereponame:Repositorio Institucional Universidad Santo Tomásspa
dc.identifier.repourlrepourl:https://repository.usta.edu.cospa
dc.identifier.urihttp://hdl.handle.net/11634/69571
dc.language.isospa
dc.publisherUniversidad Santo Tomásspa
dc.publisher.branchCRAI-USTA Tunja
dc.publisher.facultyFacultad de Ingeniería Civilspa
dc.publisher.programMaestría Ingeniería Civil con Énfasis en Hidroambientalspa
dc.relation.referencesAcosta, D. (2016). Impactos ambientales de la minería de carbón y su relación con los problemas de salud de la población del municipio de Samacá (Boyacá),según reportes ASIS 2005-2011. Universidad Distrital Francisco José de Caldas.
dc.relation.referencesAdel, M., Ahmed, M. A., Elabiad, M. A., & Mohamed, A. A. (2022). Removal of heavy metals and dyes from wastewater using graphene oxide-based nanomaterials: A critical review. Environmental Nanotechnology, Monitoring & Management, 100719. https://doi.org/10.1016/J.ENMM.2022.100719
dc.relation.referencesAduvire, O. (2006). Drenaje ácido de mina generación y tratamiento . http://info.igme.es/SidPDF/113000/258/113258_0000001.pdf
dc.relation.referencesAhne, J., Li, Q., Croiset, E., & Tan, Z. (2019). Electrospun cellulose acetate nanofibers for airborne nanoparticle filtration. Textile Research Journal, 89(15), 3137–3149. https://doi.org/10.1177/0040517518807440
dc.relation.referencesAlcaldía Municipal de Samacá. (2015). EOT- Samacá. 008, 101–115.
dc.relation.referencesAli, I. (2012). New generation adsorbents for water treatment. Chemical Reviews, 112(10), 5073–5091. https://doi.org/10.1021/CR300133D/ASSET/IMAGES/CR300133D.SOCIAL.JPEG_V03
dc.relation.referencesAmin, N. A. A. M., Mokhter, M. A., Salamun, N., & Mahmood, W. M. A. W. (2021). Phosphate Adsorption from Aqueous Solution Using Electrospun Cellulose Acetate Nanofiber Membrane Modified with Graphene Oxide/Sodium Dodecyl Sulphate. Membranes 2021, Vol. 11, Page 546, 11(7), 546. https://doi.org/10.3390/MEMBRANES11070546
dc.relation.referencesAnusiya, G., & Jaiganesh, R. (2022). A review on fabrication methods of nanofibers and a special focus on application of cellulose nanofibers. In Carbohydrate Polymer Technologies and Applications (Vol. 4). Elsevier Ltd. https://doi.org/10.1016/j.carpta.2022.100262
dc.relation.referencesAPHA, AWWA, & WEF. (2012). Standard Methods for the examination of water and wastewater (American Public Health Association, Ed.; 22nd ed.). https://doi.org/10.2105/SMWW.2882.216
dc.relation.referencesArias, J. (2015, August 13). Carbón y desarrollo en Colombia . Zero. https://bit.ly/3u7vQPr
dc.relation.referencesAseri, N. S., Lau, W. J., Goh, P. S., Hasbullah, H., Othman, N. H., & Ismail, A. F. (2019). Preparation and characterization of polylactic acid-modified polyvinylidene fluoride hollow fiber membranes with enhanced water flux and antifouling resistance. Journal of Water Process Engineering, 32. https://doi.org/10.1016/j.jwpe.2019.100912
dc.relation.referencesBarahuie, F., Saifullah, B., Dorniani, D., Fakurazi, S., Karthivashan, G., Hussein, M. Z., & Elfghi, F. M. (2017). Graphene oxide as a nanocarrier for controlled release and targeted delivery of an anticancer active agent, chlorogenic acid. Materials Science and Engineering C, 74, 177–185. https://doi.org/10.1016/j.msec.2016.11.114
dc.relation.referencesBellich, S. (2023). Evaluación de la concentración de elementos contaminantes en muestras de carbón procesadas por un sistema de limpieza avanzado. https://repositorio.uniatlantico.edu.co/bitstream/handle/20.500.12834/1615/1%20TS%20SILVIA%20PATRICIA%20BELLICH%20FERNANDEZ%20ok.pdf?sequence=1&isAllowed=y
dc.relation.referencesBhardwaj, N., & Kundu, S. C. (2010). Electrospinning: A fascinating fiber fabrication technique. In Biotechnology Advances (Vol. 28, Issue 3, pp. 325–347). https://doi.org/10.1016/j.biotechadv.2010.01.004
dc.relation.referencesBurns, A. S., Pugh, C. W., Segid, Y. T., Behum, P. T., Lefticariu, L., & Bender, K. S. (2012). Performance and microbial community dynamics of a sulfate-reducing bioreactor treating coal generated acid mine drainage. Biodegradation, 23(3), 415–429. https://doi.org/10.1007/S10532-011-9520-Y/METRICS
dc.relation.referencesBurritt, R. L., & Christ, K. L. (2018). Water risk in mining: Analysis of the Samarco dam failure. Journal of Cleaner Production, 178, 196–205. https://doi.org/10.1016/j.jclepro.2018.01.042
dc.relation.referencesCAR, IAVH, CORPOCHIVOR, & CORPOBOYACÁ. (2008). Estudio sobre el estado actual del macizo del Páramo Rabanal .
dc.relation.referencesChavez, G. (2018). Nanotechnology an alternative for wastewater treatment: Advances, Advantages and Disadvantages. Scielo.
dc.relation.referencesChen, H. C., Tsai, C. H., & Yang, M. C. (2011). Mechanical properties and biocompatibility of electrospun polylactide/poly(vinylidene fluoride) mats. Journal of Polymer Research, 18(3), 319–327. https://doi.org/10.1007/s10965-010-9421-5
dc.relation.referencesChen, H. li, & Jiao, X. ning. (2017). Preparation and characterization of Polyvinylidene fluoride/Octaphenyl-Polyhedral oligomeric silsesquioxane hybrid Lithium-ion battery separators by electrospinning. Solid State Ionics, 310, 134–142. https://doi.org/10.1016/j.ssi.2017.08.017
dc.relation.referencesChoksi, N., & Desai, H. (2017). Synthesis of Biodegradable Polylactic Acid Polymer By Using Lactic Acid Monomer. In International Journal of Applied Chemistry (Vol. 13, Issue 2). http://www.ripublication.com
dc.relation.referencesChristoforou, T., & Doumanidis, C. (2010). Biodegradable cellulose acetate nanofiber fabrication via electrospinning. Journal of Nanoscience and Nanotechnology, 10(9), 6226–6233. https://doi.org/10.1166/jnn.2010.2577
dc.relation.referencesConcha, V. O. C., Timóteo, L., Duarte, L. A. N., Bahú, J. O., Munoz, F. L., Silva, A. P., Lodi, L., Severino, P., León-Pulido, J., & Souto, E. B. (2024). Properties, characterization and biomedical applications of polyvinylidene fluoride (PVDF): a review. In Journal of Materials Science (Vol. 59, Issue 31, pp. 14185–14204). Springer. https://doi.org/10.1007/s10853-024-10046-3
dc.relation.referencesCondorchem Enviro Solutions. (2022). Tratamiento de aguas residuales generadas en explotaciones mineras.
dc.relation.referencesCorradine, A. (2011). De las ferrerías a la siderúrgica. Revista Credencial Historia . https://bit.ly/3tjKX98
dc.relation.referencesDamaraju, S. M., Wu, S., Jaffe, M., & Arinzeh, T. L. (2013). Structural changes in PVDF fibers due to electrospinning and its effect on biological function. Biomedical Materials (Bristol), 8(4). https://doi.org/10.1088/1748-6041/8/4/045007
dc.relation.referencesDarío, J., & Betancourt, B. (2020). Minería, comercio internacional e impactos ambientales en el páramo El Rabanal de Samacá, Boyac. Intropica: Revista Del Instituto de Investigaciones Tropicales, ISSN-e 2389-7864, ISSN 1794-161X, Vol. 15, No. 1, 2020, Págs. 42-54, 15(1), 42–54. https://doi.org/10.21676/23897864.3426
dc.relation.referencesErsan, G., Apul, O. G., Perreault, F., & Karanfil, T. (2017). Adsorption of organic contaminants by graphene nanosheets: A review. Water Research, 126, 385–398. https://doi.org/10.1016/J.WATRES.2017.08.010
dc.relation.referencesEspinosa, A. (2018). PROBLEMÁTICA AMBIENTAL PARAMO DE RABANAL EN SAMACÁ: VISIÓN DESDE LA ASOCIACIÓN DE USUARIOS DEL DISTRITO DE ADECUACIÓN DE TIERRAS DE SAMACÁ, (ASUSA). https://bit.ly/3Ipmsfg
dc.relation.referencesFatahian, R., Mirjalili, M., Khajavi, R., Rahimi, M. K., & Nasirizadeh, N. (2021). Effect of electrospinning parameters on production of polyvinyl alcohol/polylactic acid nanofiber using a mutual solvent. Polymers and Polymer Composites, 29(9_suppl), S844–S856. https://doi.org/10.1177/09673911211027126
dc.relation.referencesFayemi, O. E., Ogunlaja, A. S., Kempgens, P. F. M., Antunes, E., Torto, N., Nyokong, T., & Tshentu, Z. R. (2013). Adsorption and separation of platinum and palladium by polyamine functionalized polystyrene-based beads and nanofibers. Minerals Engineering, 53, 256–265. https://doi.org/10.1016/j.mineng.2013.06.006
dc.relation.referencesFong, H., Chun, I., & Reneker, D. H. (n.d.). Beaded nanofibers formed during electrospinning.
dc.relation.referencesFryczkowski, R., Gorczowska, M., Fryczkowska, B., & Janicki, J. (2013). The effect of solvent on the properties of nanofibres obtained by electrospinning from a mixture of poly(3-hydroxybutyrate) and polyaniline. Synthetic Metals, 166(1), 14–21. https://doi.org/10.1016/j.synthmet.2013.01.011
dc.relation.referencesGee, S., Johnson, B., & Smith, A. L. (2018). Optimizing electrospinning parameters for piezoelectric PVDF nanofiber membranes. Journal of Membrane Science, 563, 804–812. https://doi.org/10.1016/j.memsci.2018.06.050
dc.relation.referencesGOBERNACIÓN DE BOYACÁ, D. T. D. S. P. (n.d.). Mapa de riesgo de calidad de agua para consumo humano municipio de Samacá - Boyacá zona urbana.
dc.relation.referencesGong, M., Zhao, Q., Dai, L., Li, Y., & Jiang, T. (2017). Fabrication of polylactic acid/hydroxyapatite/graphene oxide composite and their thermal stability, hydrophobic and mechanical properties. Journal of Asian Ceramic Societies, 5(2), 160–168. https://doi.org/10.1016/j.jascer.2017.04.001
dc.relation.referencesGreiner, A., & Wendorff, J. H. (2007). Electrospinning: A fascinating method for the preparation of ultrathin fibers. In Angewandte Chemie - International Edition (Vol. 46, Issue 30, pp. 5670–5703). https://doi.org/10.1002/anie.200604646
dc.relation.referencesGuerrero Tamayo, C. (2012). Construcción de un modelo de mezcla de carbones colombianos para la producción de coque. Aplicación de análisis petrográficos, reológicos y termogravimétricos [Universidad Nacional de Colombia ]. https://repositorio.unal.edu.co/bitstream/handle/unal/11456/197434.2012.pdf?sequence=1&isAllowed=y
dc.relation.referencesGuzmán, K. (2014). Determinación de hierro en aguas del sector urbano del lago Titicaca (parte del sistema TDPS) mediante la formación de complejo, utilizando la técnica espectrofotométrica [Universidad Mayor de San Andrés]. https://repositorio.umsa.bo/bitstream/handle/123456789/10782/EG-1416-Guzman%20Machaca%2C%20Ana%20Karem.pdf?sequence=1&isAllowed=y#:~:text=5.%2D%20Ley%20de%20Beer&text=De%20acuerdo%20con%20esta%20ley,b)%20en%20el%20medio%20absorbente.
dc.relation.referencesHaider, A., Haider, S., & Kang, I. K. (2018). A comprehensive review summarizing the effect of electrospinning parameters and potential applications of nanofibers in biomedical and biotechnology. In Arabian Journal of Chemistry (Vol. 11, Issue 8, pp. 1165–1188). Elsevier B.V. https://doi.org/10.1016/j.arabjc.2015.11.015
dc.relation.referencesHuérfano-Aguilar, S. (2022). Extractivismo, acero y ambiente: Acerías Paz del Río y el auge industrial en el Valle de Sogamoso, Boyacá (1954-1983). Anuario de Historia Regional y de Las Fronteras, 28(1). https://doi.org/10.18273/revanu.v28n1-2023008
dc.relation.referencesHummers, W. S., & Offeman, R. E. (1958). Preparation of Graphitic Oxide. Journal of the American Chemical Society, 80(6), 1339. https://doi.org/10.1021/JA01539A017
dc.relation.referencesINGEOMINAS, ECOCARBON, & COLCIENCIAS. (1994). Características y usos tecnológicos de los carbones de la zona Cundinamarca- Boyacá.
dc.relation.referencesJaeger, R., Berfshoef, M., Batle, C., SchÖnherr, H., & Vancso, J. (1998). Electrospinning of ultra-thin polymer fibers. Macromolecular Symposia, 141–150.
dc.relation.referencesJoshi, N. C., & Gururani, P. (2022a). Advances of graphene oxide based nanocomposite materials in the treatment of wastewater containing heavy metal ions and dyes. In Current Research in Green and Sustainable Chemistry (Vol. 5). Elsevier B.V. https://doi.org/10.1016/j.crgsc.2022.100306
dc.relation.referencesKabir, E., Khatun, M., Nasrin, L., Raihan, M. J., & Rahman, M. (2017). Pure β-phase formation in polyvinylidene fluoride (PVDF)-carbon nanotube composites. In Journal of Physics D: Applied Physics (Vol. 50, Issue 16). Institute of Physics Publishing. https://doi.org/10.1088/1361-6463/aa5f85
dc.relation.referencesKitsara, M., Blanquer, A., Murillo, G., Humblot, V., De Bragança Vieira, S., Nogués, C., Ibáñez, E., Esteve, J., & Barrios, L. (2019). Permanently hydrophilic, piezoelectric PVDF nanofibrous scaffolds promoting unaided electromechanical stimulation on osteoblasts. Nanoscale, 11(18), 8906–8917. https://doi.org/10.1039/c8nr10384d
dc.relation.referencesKo, F. K., & Wan, Y. (2014). Introduction to Nanofiber Materials. In Introduction to Nanofiber Materials (pp. 1–12). Cambridge University Press. https://doi.org/10.1017/cbo9781139021333.002
dc.relation.referencesKrishnamoorthy, K., Veerapandian, M., Yun, K., & Kim, S. J. (2013). The chemical and structural analysis of graphene oxide with different degrees of oxidation. Carbon, 53, 38–49. https://doi.org/10.1016/j.carbon.2012.10.013
dc.relation.referencesLeguizamo, A., & Ruiz, J. (2018). Impactos ambientales de la minería de carbón sobre el recurso hídrico en el departamento de Boyacá (Vol. 12, Issue 1).
dc.relation.referencesLolla, D., Lolla, M., Abutaleb, A., Shin, H. U., Reneker, D. H., & Chase, G. G. (2016). Fabrication, polarization of electrospun polyvinylidene fluoride electret fibers and effect on capturing nanoscale solid aerosols. Materials, 9(8). https://doi.org/10.3390/ma9080671
dc.relation.referencesLuo, L., Gu, X., Wu, J., Zhong, S., & Chen, J. (2012). Advances in Graphene for Adsorption of Heavy Metals in Wastewater. Advanced Materials Research, 550–553, 2121–2124. https://doi.org/10.4028/WWW.SCIENTIFIC.NET/AMR.550-553.2121
dc.relation.referencesManosalva, S. (2018). Fluidez de los carbones bituminosos colombianos y relación con reflectancia de vitrinita y composición maceral [Universidad Pedagógica y Tecnológica de Colombia]. https://repositorio.uptc.edu.co/handle/001/3058
dc.relation.referencesManrique, R. (2021a). Inventario y caracterización hidrogeoquímica de los drenajes de minería de carbón en los municipios de la provincia Centro de Boyacá Colombia. Universidad Nacional de Colombia.
dc.relation.referencesManuel, O.-G., Jorge Ricardo, A.-H., & Tetyana, K. (n.d.). Ingeniería Investigación y Tecnología, volumen XIV (número 4), octubre-diciembre 2013: 575-581.
dc.relation.referencesMatabola, K. P., & Moutloali, R. M. (2013). The influence of electrospinning parameters on the morphology and diameter of poly(vinyledene fluoride) nanofibers- Effect of sodium chloride. Journal of Materials Science, 48(16), 5475–5482. https://doi.org/10.1007/s10853-013-7341-6
dc.relation.referencesMedeiros, K. A. R., Rangel, E. Q., Sant’Anna, A. R., Louzada, D. R., Barbosa, C. R. H., & D’Almeida, J. R. M. (2018). Evaluation of the electromechanical behavior of polyvinylidene fluoride used as a component of risers in the offshore oil industry. Oil and Gas Science and Technology, 73(2). https://doi.org/10.2516/ogst/2018058
dc.relation.referencesMegelski, S., Stephens, J. S., Bruce Chase, D., & Rabolt, J. F. (2002). Micro- and nanostructured surface morphology on electrospun polymer fibers. Macromolecules, 35(22), 8456–8466. https://doi.org/10.1021/ma020444a
dc.relation.referencesMilazzo, M., Danti, S., Livens, P., Dirckx, J., Scaffaro, R., & Gammino, M. (2024). Electrospun graphene oxide/polymeric nanocomposites for eardrum replacements. Composites Communications, 51. https://doi.org/10.1016/j.coco.2024.102048
dc.relation.referencesMinisterio de Ambiente, V. y D. T. y M. de P. S. (2007). Resolución 2115 de 2007. https://minvivienda.gov.co/normativa/resolucion-2115-2007
dc.relation.referencesMinisterio de minas y de energia, & Instituto Colombiano de geología y minería. (2004). El carbón colombiano recursos, reservas y calidad.
dc.relation.referencesMohammadi, T., & Safavi, M. A. (2009). Application of Taguchi method in optimization of desalination by vacuum membrane distillation. Desalination, 249(1), 83–89. https://doi.org/10.1016/j.desal.2009.01.017
dc.relation.referencesMohammed, A. M., Thalji, M. R., Yasin, S. A., Shim, J. J., Chong, K. F., Guda, A. A., & Ali, G. A. M. (2023). Recent advances in electrospun fibrous membranes for effective chromium (VI) removal from water. In Journal of Molecular Liquids (Vol. 383). Elsevier B.V. https://doi.org/10.1016/j.molliq.2023.122110
dc.relation.referencesMuñoz, J. (2007). Diseño de agenda para el desarrollo productivo y competitivo del distrito minero Zipa - Samacá contrato # 1517-09-2007
dc.relation.referencesNaseem, T., & Waseem, M. (2021). A comprehensive review on the role of some important nanocomposites for antimicrobial and wastewater applications. International Journal of Environmental Science and Technology 2021 19:3, 19(3), 2221–2246. https://doi.org/10.1007/S13762-021-03256-8
dc.relation.referencesNguyen, T. T. T., Nguyen, H. T., Trinh, H. T., Bui, T. T. T., Le, A. T., & Huy, T. Q. (2022). Effect of the Morphological Characteristic and Composition of Electrospun Polyvinylidene Fluoride/Graphene Oxide Membrane on Its Pb2+ Adsorption Capacity. Macromolecular Research 2022 30:2, 30(2), 124–135. https://doi.org/10.1007/S13233-022-0012-1
dc.relation.referencesNik, G., Nik, R., Jami, M., Engliman, N., Amosa, M., & Isa, M. (2021). Study of graphene oxide-polymer nanocomposite (GPN) adsorptive membrane for lead removal from wastewater. Revista de Ciencia y Tecnología de La Ingeniería. http://irep.iium.edu.my/88586/
dc.relation.referencesObaideen, K., Shehata, N., Sayed, E. T., Abdelkareem, M. A., Mahmoud, M. S., & Olabi, A. G. (2022). The role of wastewater treatment in achieving sustainable development goals (SDGs) and sustainability guideline. Energy Nexus, 7, 100112. https://doi.org/10.1016/J.NEXUS.2022.100112
dc.relation.referencesOrozco, V. (2020). EVALUACIÓN INTEGRAL DE LA CALIDAD DEL AGUA EN EL ÁREA DE INFLUENCIA DIRECTA DEL RÍO GACHANECA DEL MUNICIPIO DE SAMACÁ [Universidad Santo Tomas Sede Tunja]. https://bit.ly/3GAhDjR
dc.relation.referencesPan, B., Pan, B., Zhang, W., Lv, L., Zhang, Q., & Zheng, S. (2009). Development of polymeric and polymer-based hybrid adsorbents for pollutants removal from waters. Chemical Engineering Journal, 151(1–3), 19–29. https://doi.org/10.1016/J.CEJ.2009.02.036
dc.relation.referencesPinzón, A. (2021). Evaluación de los efectos antrópicos en los parámetros de calidad del agua del valle de Samacá, Boyacá. Universidad Santo Tomás - Seccional Tunja.
dc.relation.referencesPrasad, S., Yadav, K. K., Kumar, S., Gupta, N., Cabral-Pinto, M. M. S., Rezania, S., Radwan, N., & Alam, J. (2021). Chromium contamination and effect on environmental health and its remediation: A sustainable approaches. In Journal of Environmental Management (Vol. 285). Academic Press. https://doi.org/10.1016/j.jenvman.2021.112174
dc.relation.referencesPromnil, S., Numpaisal, P. O., & Ruksakulpiwat, Y. (2021). Effect of molecular weight on mechanical properties of electrospun poly (lactic acid) fibers for meniscus tissue engineering scaffold. Materials Today: Proceedings, 47, 3496–3499. https://doi.org/10.1016/j.matpr.2021.03.504
dc.relation.referencesRamazani, S., & Karimi, M. (2016). Electrospinning of poly(ε-caprolactone) solutions containing graphene oxide: Effects of graphene oxide content and oxidation level. Polymer Composites, 37(1), 131–140. https://doi.org/10.1002/pc.23163
dc.relation.referencesRen, X., & Dzenis, Y. (2006). Novel Continuous Poly(vinylidene fluoride) Nanofibers.
dc.relation.referencesReneker, D. H., & Chun, I. (1996). Nanometre diameter fibres of polymer, produced by electrospinning. In Nanotechnology (Vol. 7). http://iopscience.iop.org/0957-4484/7/3/009
dc.relation.referencesRocca-Smith, J. R., Lagorce-Tachon, A., Iaconelli, C., Bellat, J. P., Marcuzzo, E., Sensidoni, A., Piasente, F., Debeaufort, F., & Karbowiak, T. (2017). How high pressure CO2 impacts PLA film properties. Express Polymer Letters, 11(4), 320–333. https://doi.org/10.3144/expresspolymlett.2017.31
dc.relation.referencesRoig, B. (2006). Evaluación de las tecnologías de tratamiento de aguas subterráneas contaminadas con Cromo. https://upcommons.upc.edu/entities/publication/12267c7f-e0c8-4c0e-bd36-64f9b272fe7f
dc.relation.referencesSalamanca, P. (1999). DIAGNÓSTICO GEOLÓGICO-MINERO DE LOS CARBONES METALÚRGICOS Y ESPECIALES EN EL DEPARTAMENTO DE BOYACÁ.
dc.relation.referencesSaleh, T. A., Mustaqeem, M., & Khaled, M. (2022). Water treatment technologies in removing heavy metal ions from wastewater: A review. Environmental Nanotechnology, Monitoring & Management, 17, 100617. https://doi.org/10.1016/J.ENMM.2021.100617
dc.relation.referencesSalehi, M., Sharafoddinzadeh, D., Mokhtari, F., Esfandarani, M. S., & Karami, S. (2021). Electrospun nanofibers for efficient adsorption of heavy metals from water and wastewater. Clean Technologies and Recycling, 1(1), 1–33. https://doi.org/10.3934/ctr.2021001
dc.relation.referencesSánchez-Cepeda, A., Cedeño, E., Marín, E., Pazos, M. C., Ingrid, S. C., Muñoz, E. de J., & Vera-Graziano, R. (2024). Evaluation of the dispersion properties of graphene oxide/cetyltrimethylammonium bromide for application in nanocomposite materials. RSC Advances, 14(5), 3267–3279. https://doi.org/10.1039/d3ra04689c
dc.relation.referencesSantana, C. S., Montalván Olivares, D. M., Silva, V. H. C., Luzardo, F. H. M., Velasco, F. G., & de Jesus, R. M. (2020). Assessment of water resources pollution associated with mining activity in a semi-arid region. Journal of Environmental Management, 273, 111148. https://doi.org/10.1016/J.JENVMAN.2020.111148
dc.relation.referencesSarria-Villa, R. A., Gallo-Corredor, j. s., & Benítez-Benítez, R. (2020). Tecnologías para remover metales pesados presentes en aguas. Caso Cromo y Mercurio. Journal de Ciencia e Ingeniería, 12(1), 94–109. https://doi.org/10.46571/jci.2020.1.8
dc.relation.referencesScaffaro, R., Gammino, M., & Maio, A. (2023). Hierarchically Structured Hybrid Membranes for Continuous Wastewater Treatment via the Integration of Adsorption and Membrane Ultrafiltration Mechanisms. Polymers, 15(1). https://doi.org/10.3390/polym15010156
dc.relation.referencesSelatile, K., Ray, S. S., Ojijo, V., & Sadiku, R. E. (2021). Morphological, Thermal, and Mechanical Properties of Electrospun Recycled Poly(ethylene terephthalate)/Graphene Oxide Composite Nanofiber Membranes. ACS Omega, 6(32), 21005–21015. https://doi.org/10.1021/acsomega.1c02578
dc.relation.referencesShen, J., Chen, R. X., & He, J. H. (2014). Bio-mimic design of PM2.5 anti-smog masks. Thermal Science, 18(5), 1689–1690. https://doi.org/10.2298/TSCI1405689S
dc.relation.referencesSill, T. J., & von Recum, H. A. (2008). Electrospinning: Applications in drug delivery and tissue engineering. In Biomaterials (Vol. 29, Issue 13, pp. 1989–2006). https://doi.org/10.1016/j.biomaterials.2008.01.011
dc.relation.referencesSilva, E., & Rosas, O. (2016). ELECTRODOS TRANSPARENTES CONDUCTORES BASADOS EN ÓXIDO DE GRAFENO REDUCIDO PARA DEPÓSITO ELECTROQUÍMICO DE ÓXIDOS SEMICONDUCTORES DE INTERÉS FOTOVOLTAICO. CIMAV REPOSITORIO. https://cimav.repositorioinstitucional.mx/jspui/handle/1004/186
dc.relation.referencesSitko, R., Turek, E., Zawisza, B., Malicka, E., Talik, E., Heimann, J., Gagor, A., Feist, B., & Wrzalik, R. (2013). Adsorption of divalent metal ions from aqueous solutions using graphene oxide. Dalton Transactions, 42(16), 5682–5689. https://doi.org/10.1039/c3dt33097d
dc.relation.referencesStopes, M. (1935). On the Petrology of Banded Bituminous Coal (Combustible, Vol. 14). https://books.google.com.co/books/about/On_the_Petrology_of_Banded_Bituminous_Co.html?id=fxI5bgAACAAJ&redir_esc=y
dc.relation.referencesSuárez, I., & Ward, C. (2008). Basic Factors Controlling Coal Quality and Technological Behavior of Coal. Applied Coal Petrology, 19–59. https://doi.org/10.1016/B978-0-08-045051-3.00002-6
dc.relation.referencesSuárez, M. (2012). “Validación de métodos analíticos para la determinación de hierro, sulfatos, turbiedad, dureza total y cálcica en muestras de aguas claras y residuales.”
dc.relation.referencesSukpancharoen, S., Wijakmatee, T., Katongtung, T., Ponhan, K., Rattanachoung, N., & Khojitmate, S. (2024). Data-driven prediction of electrospun nanofiber diameter using machine learning: A comprehensive study and web-based tool development. Results in Engineering, 24. https://doi.org/10.1016/j.rineng.2024.102826
dc.relation.referencesTejada, C., Villabona, Á., & Garcés, L. (2015). Adsorción de metales pesados en aguas residuales usando materiales de origen biológico. TecnoLógicas, 18, 109–123. https://doi.org/https://doi.org/10.22430/22565337.209
dc.relation.referencesThomas, L. (2013). Coal Geology. Journal of the Geological Society of Japan, 86(6), 433–434. https://books.google.com/books/about/Coal_Geology.html?hl=es&id=s25nfjP2kDsC
dc.relation.referencesTissot, B. P., & Welte, D. H. (1984). Petroleum formation and occurrence. 699. https://books.google.com/books/about/Petroleum_Formation_and_Occurrence.html?hl=es&id=HkVInwEACAAJ
dc.relation.referencesUbonchonlakate, K., Sikong, L., & Saito, F. (2012). Photocatalytic disinfection of P.aeruginosa bacterial Ag-doped TiO 2 film. Procedia Engineering, 32, 656–662. https://doi.org/10.1016/j.proeng.2012.01.1323
dc.relation.referencesValizadeh, A., & Mussa, S. (2012). Electrospinning and electrospun nanofibres. IET Nanobiotechnology, 90. https://doi.org/10.1049/iet-nbt.2012.0040
dc.relation.referencesWang, L., Deng, N., Ju, J., Wang, G., Cheng, B., & Kang, W. (2019). A novel core-shell structured poly-m-phenyleneisophthalamide@polyvinylidene fluoride nanofiber membrane for lithium ion batteries with high-safety and stable electrochemical performance. Electrochimica Acta, 300, 263–273. https://doi.org/10.1016/j.electacta.2019.01.115
dc.relation.referencesWang, N., Yang, Y., Al-Deyab, S. S., El-Newehy, M., Yu, J., & Ding, B. (2015). Ultra-light 3D nanofibre-nets binary structured nylon 6-polyacrylonitrile membranes for efficient filtration of fine particulate matter. Journal of Materials Chemistry A, 3(47), 23946–23954. https://doi.org/10.1039/c5ta06543g
dc.relation.referencesWard, C. R., & Suárez-Ruiz, I. (2008). Introduction to Applied Coal Petrology. Applied Coal Petrology, 1–18. https://doi.org/10.1016/B978-0-08-045051-3.00001-4
dc.relation.referencesWong, D., Andriyana, A., Ang, B. C., & Verron, E. (2016). Surface morphology and mechanical response of randomly oriented electrospun nanofibrous membrane. Polymer Testing, 53, 108–115. https://doi.org/10.1016/j.polymertesting.2016.05.020
dc.relation.referencesXiang, T., Zhang, Z., Liu, H., Yin, Z., Li, L., & Liu, X. (2013). CHARACTERIZATION OF CELLULOSE-BASED ELECTROSPUN NANOFIBERS. MEMBRANE AND ITS ADSORPTION BEHAVIORS USING CU(II), CD(II), PB(II) AS MODEL. Ciencia China Química, 56.
dc.relation.referencesXu, X., Lv, H., Zhang, M., Wang, M., Zhou, Y., Liu, Y., & Yu, D. (2023). Recent progress in electrospun nanofibers and their applications in heavy metal wastewater treatment. Frontiers of Chemical Science and Engineering .
dc.relation.referencesXue, J., Wu, T., Dai, Y., & Xia, Y. (2019). Electrospinning and electrospun nanofibers: Methods, materials, and applications. In Chemical Reviews (Vol. 119, Issue 8, pp. 5298–5415). American Chemical Society. https://doi.org/10.1021/acs.chemrev.8b00593
dc.relation.referencesXue, Z., Sun, Z., Cao, Y., Chen, Y., Tao, L., Li, K., Feng, L., Fu, Q., & Wei, Y. (2013). Superoleophilic and superhydrophobic biodegradable material with porous structures for oil absorption and oil-water separation. RSC Advances, 3(45), 23432–23437. https://doi.org/10.1039/c3ra41902a
dc.relation.referencesYu, H., & Tan, Z. (2025). Introduction to Electrospinning and Nanofiber. Springer Cham.
dc.relation.referencesZhang, K., Dwivedi, V., Chi, C., & Wu, J. (2010a). Graphene oxide/ferric hydroxide composites for efficient arsenate removal from drinking water. Journal of Hazardous Materials, 182(1–3), 162–168. https://doi.org/10.1016/J.JHAZMAT.2010.06.010
dc.relation.referencesZhao, G., Li, J., Ren, X., Chen, C., & Wang, X. (2011). Few-layered graphene oxide nanosheets as superior sorbents for heavy metal ion pollution management. Environmental Science and Technology, 45(24), 10454–10462. https://doi.org/10.1021/ES203439V/SUPPL_FILE/ES203439V_SI_001.PDF
dc.relation.referencesZhu, F., Zheng, Y. M., Zhang, B. G., & Dai, Y. R. (2021). A critical review on the electrospun nanofibrous membranes for the adsorption of heavy metals in water treatment. Journal of Hazardous Materials, 401, 123608. https://doi.org/10.1016/J.JHAZMAT.2020.123608
dc.relation.referencesZhu, L., Liu, F., Yu, X., & Xue, L. (2015). Poly(Lactic Acid) Hemodialysis Membranes with Poly(Lactic Acid)-block-Poly(2-Hydroxyethyl Methacrylate) Copolymer As Additive: Preparation, Characterization, and Performance. ACS Applied Materials and Interfaces, 7(32), 17748–17755. https://doi.org/10.1021/acsami.5b03951
dc.relation.referencesZhu, Y., Murali, S., Cai, W., Li, X., Suk, J. W., Potts, J. R., & Ruoff, R. S. (2010). Graphene and Graphene Oxide: Synthesis, Properties, and Applications. Advanced Materials, 22(35), 3906–3924. https://doi.org/10.1002/ADMA.201001068
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.rights.coarhttp://purl.org/coar/access_right/c_abf2
dc.rights.localAbierto (Texto Completo)spa
dc.subject.keywordElectrospinning
dc.subject.keywordHeavy metals ions
dc.subject.keywordWastewater
dc.subject.keywordMining
dc.subject.proposalElectrohilado
dc.subject.proposalIones de metales pesados
dc.subject.proposalAgua residual
dc.subject.proposalMinería
dc.titleFORMULACIÓN DE UNA MEMBRANA POLIMÉRICA ELECTROHILADA PARA EL ESTUDIO DE ADSORCIÓN DE HIERRO Y CROMO EN AGUAS RESIDUALES PRODUCTO DE LA MINERÍA EN EL MUNICIPIO SAMACÁ Y CHIVATÁ, BOYACÁ
dc.typemaster thesis
dc.type.coarhttp://purl.org/coar/resource_type/c_bdcc
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.driveinfo:eu-repo/semantics/masterThesis
dc.type.localTesis de maestríaspa
dc.type.versioninfo:eu-repo/semantics/acceptedVersion

Archivos

Bloque original

Mostrando 1 - 3 de 3
Miniatura
Nombre:
Autorizacion_Trabajo_de_Grado_Varios_autores_2025.pdf
Tamaño:
714.45 KB
Formato:
Adobe Portable Document Format
Descargar
Miniatura
Nombre:
CARTA ENTREGA DE TRABAJO DE GRADO.pdf
Tamaño:
255.64 KB
Formato:
Adobe Portable Document Format
Descargar
Miniatura
Nombre:
2025paulaacevedo.pdf
Tamaño:
2.88 MB
Formato:
Adobe Portable Document Format
Descargar

Bloque de licencias

Mostrando 1 - 1 de 1
Miniatura
Nombre:
license.txt
Tamaño:
807 B
Formato:
Item-specific license agreed upon to submission
Descripción:
Descargar

Colecciones

Maestría Ingeniería Civil con Énfasis en Hidroambiental