Síntesis y caracterización del sistema superconductor TR3X-1TR1XBaCuO dopado con óxido de grafeno por medio de reacción de estado sólido

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dc.contributor.advisorAyala Sotelo, Laura Natalia
dc.contributor.authorAyala Sotelo, Laura Natalia
dc.contributor.corporatenameUniversidad Santo Tomasspa
dc.date.accessioned2023-07-17T15:44:53Z
dc.date.available2023-07-17T15:44:53Z
dc.date.issued2023-06-26
dc.descriptionLa ingeniería electrónica está en constante evolución, y la búsqueda de materiales eficientes y versátiles es fundamental para el desarrollo de nuevas tecnologías. Los materiales superconductores son objeto de gran interés debido a su capacidad de transportar corriente eléctrica sin resistencia, lo que los convierte en una herramienta clave para una amplia variedad de aplicaciones en campos como la medicina, la generación de la energía, la computación cuántica y las comunicaciones. En este contexto, el presente trabajo de tesis se centra en la síntesis y caracterización del sistema superconductor de alta temperatura Y3Ba5Cu8O18- -Y358 y su modificación por medio de la sustitución del elemento Itrio (Y) por las dos tierras raras: Praseodimio (Pr) y Europio (Eu). Además, se estudia el efecto del dopaje con Oxido de grafeno (OG) en las muestras de Eu3Ba5Cu8O18- con diferentes concentraciones de OG (0.05% y 0.1%) ya que este material es un excelente conductor eléctrico. Las muestras son sintetizadas empleando el método de Reacción en estado sólido (RES) y se caracterizan estructuralmente mediante la técnica de Difracción de rayos X (DRX) y refinamiento Rietveld a través del programa General Structure Analysis System (GSAS). De esta manera se obtiene la información cristalográfica de los materiales: parámetros de red, estructura cristalina, ángulos, volumen de la celda, grupo espacial, tamaño promedio de cristalitos, porcentaje (%) de las fases cristalográficas y los parámetros de confianza del refinamiento. Así mismo, se examina la microestructura de las muestras por medio de imágenes obtenidas mediante la técnica de Microscopia electrónica de barrido (MEB), donde se evidencia una óptima compactación de los granos cuando las muestras se dopan con OG. Además, se emplea la técnica de Espectrometría de dispersión de energía de rayos X (EDS) para realizar el análisis semicuantitativo de la composición de las muestras, de acuerdo a la fórmula estequiométrica correspondiente a cada elemento químico presente en los materiales. Se mide la resistividad en función de la temperatura, en el rango de 0 a 300 K, donde se observa un decaimiento de la resistividad al alcanzar la Temperatura crítica (Tc) a 49 K. Finalmente, se sugiere la aplicación de la técnica de cuatro puntas para la medición precisa de la resistividad de los materiales.spa
dc.description.abstractElectronic engineering is constantly evolving, and the search for efficient and versatile materials is fundamental to the development of new technologies. Superconducting materials are the subject of great interest due to their ability to carry electric current without resistance, making them a key tool for a wide variety of applications in fields such as medicine, power generation, quantum computing and communications. In this context, the present thesis work focuses on the synthesis and characterization of the high-temperature superconducting system Y3Ba5Cu8O18- - Y358 and its modification by substituting the Yttrium (Y) element with the two rare earths: Praseodymium (Pr) and Europium (Eu). In addition, the effect of doping with Graphene Oxide (GO) on the samples of Eu3Ba5Cu8O18- with different concentrations of GO (0.05% and 0.1%) is studied, since this material is an excellent electrical conductor. The samples are synthesized using the Solid State Reaction (SSR) method and structurally characterized by the X-ray Diffraction (XRD) technique and Rietveld refinement through the General Structure Analysis System (GSAS) software. In this way, the crystallographic information of the materials is obtained: lattice parameters, crystal structure, angles, cell volume, space group, average size of crystallites, percentage (%) of the crystallographic phases, and the confidence parameters of the refinement. Likewise, the microstructure of the samples is examined through images obtained by the Scanning Electron Microscopy (SEM) technique, where optimum grain compaction is evident when the samples are doped with OG. In addition, the Energy-Dispersive X-ray Spectrometry (EDS) technique coupled to the SEM is used to perform the semi-quantitative analysis of the composition of the samples, according to the stoichiometric formula corresponding to each chemical element present in the materials. The resistivity is measured as a function of temperature, in the range of 0 to 300 K, where a decrease in resistivity is observed when reaching the Critical Temperature (Tc) at 49 K. Finally, the application of the Four-Point Probe technique is suggested for the precise measurement of the resistivity of the materials.spa
dc.description.degreelevelPregradospa
dc.description.degreenameIngeniero Electronicospa
dc.format.mimetypeapplication/pdf
dc.identifier.citationAyala Sotelo, L. (2023). Síntesis y caracterización del sistema superconductor TR3X-1TR1XBaCuO dopado con óxido de grafeno por medio de reacción de estado sólido. Universidad Santo Tomasspa
dc.identifier.instnameinstname:Universidad Santo Tomásspa
dc.identifier.reponamereponame:Repositorio Institucional Universidad Santo Tomásspa
dc.identifier.repourlrepourl:https://repository.usta.edu.cospa
dc.identifier.urihttp://hdl.handle.net/11634/51341
dc.language.isospa
dc.publisherUniversidad Santo Tomásspa
dc.publisher.branchCRAI-USTA Tunjaspa
dc.publisher.facultyFacultad de Ingeniería Electrónicaspa
dc.publisher.programPregrado Ingeniería Electrónicaspa
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dc.rightsAtribución-NoComercial-SinDerivadas 2.5 Colombia
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.rights.coarhttp://purl.org/coar/access_right/c_abf2spa
dc.rights.localAbierto (Texto Completo)spa
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.5/co/
dc.subject.keywordSuperconductorspa
dc.subject.keywordGraphene Oxidespa
dc.subject.keywordrare earthsspa
dc.subject.keywordFour-Point Probe technique.spa
dc.subject.proposalSuperconductorspa
dc.subject.proposalóxido de grafenospa
dc.subject.proposaltierras rarasspa
dc.subject.proposalTécnica de 4 puntasspa
dc.titleSíntesis y caracterización del sistema superconductor TR3X-1TR1XBaCuO dopado con óxido de grafeno por medio de reacción de estado sólidospa
dc.typebachelor thesis
dc.type.coarhttp://purl.org/coar/resource_type/c_7a1f
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.driveinfo:eu-repo/semantics/bachelorThesis
dc.type.localTesis de pregradospa
dc.type.versioninfo:eu-repo/semantics/acceptedVersion

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