Optimización del Proceso de Electrocoagulación para el Tratamiento de Drenajes Ácidos de Minas de Carbón en Samacá Boyacá

dc.contributor.advisorDíaz Bello, Sandra Consuelo
dc.contributor.advisorAvellaneda Díaz, Elisa María
dc.contributor.authorMatamoros Vargas, Lina Fernanda
dc.contributor.corporatenameUniversidad Santo Tomás
dc.contributor.cvlachttps://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0000773050
dc.contributor.googlescholarhttps://scholar.google.es/citations?user=up11esMAAAAJ&hl=es
dc.contributor.orcidhttps://orcid.org/0000-0002-8114-6655
dc.date.accessioned2026-07-10T15:31:38Z
dc.date.available2026-07-10T15:31:38Z
dc.date.issued2026-06-30
dc.descriptionEl drenaje acido de mina (DAM) representa un problema ambiental significativo debido a su alta acidez y contenido de metales pesados. En este estudio se evaluó la eficiencia del proceso de electrocoagulación para el tratamiento de DAM, empleando electrodos de aluminio (Al), hierro (Fe) y combinación hierro/aluminio (Fe/Al) en un reactor a escala de laboratorio de 2 Litros, bajo condiciones de 33 voltios y 0.9 amperios. Se realizaron tiempos de tratamiento de 50, 100 y 150 minutos, obteniéndose la mayor eficiencia de remoción a los 100 minutos. El consumo especifico energético vario entre 12.3 y 37.1 kWh/m3 estimándose una demanda de 279kWh/día a escala real. Se evaluó la viabilidad de implementar un sistema de energía solar fotovoltaica en Boyacá, determinándose la necesidad de aproximadamente 150 paneles solares. Los resultados evidencian que la electrocoagulación, integrada con energías renovables, es una alternativa viable y sostenible para el tratamiento de DAM. Durante el proceso se generó un subproducto flotante, el cual fue recolectado, secado y caracterizado mediante fluorescencia de rayos X (XRF), evidenciando la presencia predominante de óxidos metálicos como Al2O3 y Fe2O3 asociados a los mecanismos de coagulación. Este análisis permitió identificar la composición de los residuos generados, aportando información relevante para su gestión ambiental. Los resultados obtenidos evidencian que la electrocoagulación, especialmente con electrodos de aluminio a 100 minutos de operación, constituye una alternativa eficiente para el tratamiento de drenajes ácidos de mina.
dc.description.abstractAcid mine drainage (AMD) represents a significant environmental problem due to its high acidity and heavy metal content. This study evaluated the efficiency of the electrocoagulation process for AMD treatment, using aluminum (Al), iron (Fe), and iron/aluminum (Fe/Al) combination electrodes in a 2-liter laboratory-scale reactor under conditions of 33 volts and 0.9 amps. Treatment times of 50, 100, and 150 minutes were performed, with the highest removal efficiency obtained at 100 minutes. Specific energy consumption varied between 12.3 and 37.1 kWh/m³, with an estimated demand of 279 kWh/day at full scale. The feasibility of implementing a photovoltaic solar energy system in Boyacá was also evaluated, determining the need for approximately 150 solar panels. The results demonstrate that electrocoagulation, integrated with renewable energy, is a viable and sustainable alternative for the treatment of acid mine drainage (AMD). During the process, a floating byproduct was generated, which was collected, dried, and characterized using X-ray fluorescence (XRF), revealing the predominant presence of metal oxides such as Al₂O₃ and Fe₂O₃ associated with the coagulation mechanisms. This analysis allowed for the identification of the composition of the generated waste, providing relevant information for its environmental management. The results obtained demonstrate that electrocoagulation, especially with aluminum electrodes operating for 100 minutes, constitutes an efficient alternative for the treatment of acid mine drainage
dc.description.degreelevelPregradospa
dc.description.degreenameIngeniero Ambientalspa
dc.description.domainhttp://www.ustatunja.edu.co/investigacion
dc.format.mimetypeapplication/pdf
dc.identifier.citationMatamoros Vargas, L. F. (2026) Optimización del Proceso de Electrocoagulación para el Tratamiento de Drenajes Ácidos de Minas de Carbón en Samacá Boyacá [Trabajo de Grado, Universidad Santo Tomás].Repositorio Institucional
dc.identifier.instnameinstname:Universidad Santo Tomásspa
dc.identifier.reponamereponame:Repositorio Institucional Universidad Santo Tomásspa
dc.identifier.repourlrepourl:https://repository.usta.edu.cospa
dc.identifier.urihttp://hdl.handle.net/11634/73063
dc.language.isospa
dc.publisherUniversidad Santo Tomásspa
dc.publisher.branchCRAI-USTA Tunja
dc.publisher.facultyFacultad de Ingeniería Ambientalspa
dc.publisher.programPregrado de Ingeniería Ambientalspa
dc.relation.referencesAbulimiti, M., Guo, J., Cheng, C., & Zhou, D. (2026). Electrocoagulation for the simultaneous removal of copper and arsenic from acid mine drainage: Performance and mechanisms. Water Research, 293, 125452. https://doi.org/10.1016/j.watres.2026.125452
dc.relation.referencesAkcil, A., & Koldas, S. (2006). Acid Mine Drainage (AMD): causes, treatment and case studies. Journal of Cleaner Production, 14(12–13), 1139–1145. https://doi.org/10.1016/j.jclepro.2004.09.006
dc.relation.referencesAlam, P. N., Yulianis, Pasya, H. L., Aditya, R., Aslam, I. N., & Pontas, K. (2022). Acid mine wastewater treatment using electrocoagulation method. Materials Today: Proceedings, 63, S434–S437. https://doi.org/10.1016/j.matpr.2022.04.089
dc.relation.referencesBani-Melhem, K., Alnaief, M., Al-Qodah, Z., Al-Shannag, M., Elnakar, H., AlJbour, N., Alu’datt, M., Alrosan, M., & Ezelden, E. (2025). On the performance of electrocoagulation treatment of high-loaded gray water: kinetic modeling and parameters optimization via response surface methodology. Applied Water Science, 15(5). https://doi.org/10.1007/s13201-025 02451-z
dc.relation.referencesCaglak, A., Kurtoglu Akkaya, G., & Sari Erkan, H. (2025). Electrocoagulation as a stand-alone and hybrid strategy for medium-density fibreboard wastewater treatment: Performance, energy consumption and radical oxidant effects. Process Safety and Environmental Protection, 201. https://doi.org/10.1016/j.psep.2025.107531
dc.relation.referencesCho, K. T., Cotton, A., & Shibata, T. (2025). A Framework for Optimal Parameter Selection in Electrocoagulation Wastewater Treatment Using Integrated Physics-Based and Machine Learning Models. Sustainability (Switzerland), 17(10). https://doi.org/10.3390/su17104604
dc.relation.referencesChristie, P. (2001). Preface. Chemosphere, 42(2), 103. https://doi.org/10.1016/S0045 6535(00)00114-4
dc.relation.referencesDobrosz-Gómez, I., Ibarra-Taquez, H. N., & Gómez-García, M. Á. (2025). Evaluation of the environmental and economic scope of an electrocoagulation process for the treatment of wastewater from the instant coffee industry. Journal of Solid State Electrochemistry, 29(8), 3441–3463. https://doi.org/10.1007/s10008-024-05940-4
dc.relation.referencesEspinoza, L. C., Llanos, A., Cepeda, M., Carreño, A., Velásquez, P., Cruz, B., Ramírez, G., Romero, J., Abejón, R., Quijada-Maldonado, E., Aguirre, M. J., & Arce, R. (2025). Optimization of a Monopolar Electrode Configuration for Hybrid Electrochemical Treatment of Real Washing Machine Wastewater. International Journal of Molecular Sciences, 26(13). https://doi.org/10.3390/ijms26136445
dc.relation.referencesFoudhaili, T., Lefebvre, O., Coudert, L., & Neculita, C. M. (2020). Sulfate removal from mine drainage by electrocoagulation as a stand-alone treatment or polishing step. Minerals Engineering, 152, 106337. https://doi.org/10.1016/j.mineng.2020.106337
dc.relation.referencesFoudhaili, T., Rakotonimaro, T. V., Neculita, C. M., Coudert, L., & Lefebvre, O. (2019). Comparative efficiency of microbial fuel cells and electrocoagulation for the treatment of iron-rich acid mine drainage. Journal of Environmental Chemical Engineering, 7(3), 103149. https://doi.org/10.1016/j.jece.2019.103149
dc.relation.referencesGök, Z., & Gülyaşar, H. C. (2025). Preliminary Laboratory Assessment of the Removal of Heavy Metals from Metal Plating Wastewater by Electrocoagulation. Water, Air, and Soil Pollution, 236(6). https://doi.org/10.1007/s11270-025-07979-z
dc.relation.referencesGradinac, J., & Jovović, A. (2025). Electrocoagulation as a new and advanced technology for future challenges in the steel industry’s water treatment plants. Hemijska Industrija, 79(1), 1–8. https://doi.org/10.2298/HEMIND240422026G
dc.relation.referencesImteaz, M. A., Tariq, M. R., Rajabi, Z., & Ahsan, A. (2025). Mathematical Modelling for Predicting Wastewater Treatment Efficiency Through Specialised Electrocoagulation. International Journal of Environmental Research, 19(4). https://doi.org/10.1007/s41742 025-00780-0
dc.relation.referencesInna, S., Natacha, E. A. R., Harouna, M., & Richard, K. (2025). Phosphorus recovery from beef slaughterhouse wastewater by electrocoagulation process. Sustainable Chemistry for the Environment, 10. https://doi.org/10.1016/j.scenv.2025.100263
dc.relation.referencesJamrah, A., Al-Zghoul, T. M., Al-Qodah, Z., & Al-Karablieh, E. (2025). Performance of Combined Olive Mills Wastewater Treatment System: Electrocoagulation-Assisted Adsorption as a Post Polishing Sustainable Process. Water (Switzerland), 17(11). https://doi.org/10.3390/w17111697
dc.relation.referencesJi, W., Wang, Y., Kou, X., Zhao, Z., & Yuan, Y. (2025). Deep treatment of low-concentration fluorine wastewater based on the graphite bipolar-driven electrocoagulation method. Desalination and Water Treatment, 323. https://doi.org/10.1016/j.dwt.2025.101253
dc.relation.referencesJohnson, D. B., & Hallberg, K. B. (2005). Acid mine drainage remediation options: a review. Science of The Total Environment, 338(1–2), 3–14. https://doi.org/10.1016/j.scitotenv.2004.09.002
dc.relation.referencesLi, H., Di, J., Dong, Y., Bao, S., & Fu, S. (2023). Dynamic experiment on remediation of acid mine drainage by iron–carbon microelectrolysis enhancing sulfate-reducing bacteria. Environmental Science: Water Research & Technology, 9(5), 1413–1425. https://doi.org/10.1039/D2EW00947A
dc.relation.referencesLouay Abdullah, L., & Salih Bahar, S. (2025). Petroleum refinery wastewater treatment through the successive process of electrocoagulation and electrooxidation. Al-Qadisiyah Journal for Engineering Sciences, 18(2), 163–169. https://doi.org/10.30772/qjes.2024.151030.1274
dc.relation.referencesMamelkina, M. A., Cotillas, S., Lacasa, E., Sáez, C., Tuunila, R., Sillanpää, M., Häkkinen, A., & Rodrigo, M. A. (2017). Removal of sulfate from mining waters by electrocoagulation. Separation and Purification Technology, 182, 87–93. https://doi.org/10.1016/j.seppur.2017.03.044
dc.relation.referencesMelissa, C., Daniel, Y., & Milagros, K. (2025). Artículo de revisión Tratamiento de aguas residuales mediante electrocoagulación: Análisis bibliométrico de publicaciones científicas y revisión de resultados Wastewater treatment by electrocoagulation: bibliometric analysis of scientific publications and review of results. Rev. Amaz. Cienc. Ambient. Ecol, 4(1). https://doi.org/10.51252/reacae.v4i1.e802
dc.relation.referencesMineros, D. Á. (n.d.). Estandarizar los procesos relacionados con DRENAJES ÁCIDOS MINEROS (DAM).
dc.relation.referencesMollah, M. Y. A., Schennach, R., Parga, J. R., & Cocke, D. L. (2001). Electrocoagulation (EC) — science and applications. Journal of Hazardous Materials, 84(1), 29–41. https://doi.org/10.1016/S0304-3894(01)00176-5
dc.relation.referencesOncel, M. S., Muhcu, A., Demirbas, E., & Kobya, M. (2013). A comparative study of chemical precipitation and electrocoagulation for treatment of coal acid drainage wastewater. Journal of Environmental Chemical Engineering, 1(4), 989–995. https://doi.org/10.1016/j.jece.2013.08.008
dc.relation.referencesPanda, G. C., Das, S. K., & Guha, A. K. (2009). Jute stick powder as a potential biomass for the removal of congo red and rhodamine B from their aqueous solution. Journal of Hazardous Materials, 164(1), 374–379. https://doi.org/10.1016/j.jhazmat.2008.08.015
dc.relation.referencesRoncal-Herrero, T., & Oelkers, E. H. (2011). Experimental determination of struvite dissolution and precipitation rates as a function of pH. Applied Geochemistry, 26(5), 921–928. https://doi.org/10.1016/j.apgeochem.2011.03.002
dc.relation.referencesSheoran, A. S., & Sheoran, V. (2006). Heavy metal removal mechanism of acid mine drainage in wetlands: A critical review. Minerals Engineering, 19(2), 105–116. https://doi.org/10.1016/j.mineng.2005.08.006
dc.relation.referencesSolano Huerta, I. S., Roa Morales, G., Balderas Hernández, P., Barrera Díaz, C. E., Pavón Silva, T. B., Ávila Pérez, P., & Rodríguez Torres, I. (2025). Technical Considerations for Designing an Electrocoagulation Reactor for Wastewater Treatment: A Brief Review. In Processes (Vol. 13, Number 6). Multidisciplinary Digital Publishing Institute (MDPI). https://doi.org/10.3390/pr13061679
dc.relation.referencesSrivastava, N. S. L., Din, M., & Tiwari, G. N. (2000). Performance evaluation of distillation cum-greenhouse for a warm and humid climate. Desalination, 128(1), 67–80. https://doi.org/10.1016/S0011-9164(00)00024-2
dc.relation.referencesUNIVERSIDAD POLITÉCNICA DE MONCLOVA FRONTERA Memoria de estadía profesional. (n.d.).
dc.relation.referencesWood, L. E. (2023). Advanced acid mine remediation. Proceedings of the International Conference on Mine Closure, 2023-October. https://doi.org/10.36487/ACG_repo/2315_056
dc.relation.referencesYounger, P. L., Banwart, S. A., & Hedin, R. S. (2002). Mine Water (Vol. 5). Springer Netherlands. https://doi.org/10.1007/978-94-010-0610-1
dc.rightsAttribution-NonCommercial-NoDerivs 2.5 Colombiaen
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.rights.coarhttp://purl.org/coar/access_right/c_abf2
dc.rights.localAbierto (Texto Completo)spa
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.5/co/
dc.subject.keywordElectrocoagulation
dc.subject.keywordAcid mine drainage
dc.subject.keywordAluminum electrodes
dc.subject.keywordWater treatment
dc.subject.keywordEnergy consumption
dc.subject.proposalElectrocoagulación
dc.subject.proposalDrenaje acido de mina (DAM)
dc.subject.proposalElectrodos de aluminio
dc.subject.proposalTratamiento de aguas
dc.subject.proposalConsumo energético
dc.titleOptimización del Proceso de Electrocoagulación para el Tratamiento de Drenajes Ácidos de Minas de Carbón en Samacá Boyacá
dc.typebachelor thesis
dc.type.coarhttp://purl.org/coar/resource_type/c_7a1f
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.driveinfo:eu-repo/semantics/bachelorThesis
dc.type.localTrabajo de Gradospa
dc.type.versioninfo:eu-repo/semantics/acceptedVersion

Archivos

Bloque original

Mostrando 1 - 3 de 3
Cargando...
Miniatura
Nombre:
2026LinaMatamoros
Tamaño:
1.35 MB
Formato:
Adobe Portable Document Format
Cargando...
Miniatura
Nombre:
Autorización facultad
Tamaño:
330.61 KB
Formato:
Adobe Portable Document Format
Cargando...
Miniatura
Nombre:
Autorización estudiante
Tamaño:
333.69 KB
Formato:
Adobe Portable Document Format

Bloque de licencias

Mostrando 1 - 1 de 1
Cargando...
Miniatura
Nombre:
license.txt
Tamaño:
807 B
Formato:
Item-specific license agreed upon to submission
Descripción: