Performance of La0.5Sr1.5MnO4±d Ruddlesden-Popper manganite as electrode material for symmetrical solid oxide fuel cells. Part A. The oxygen reduction reaction
| dc.contributor.author | Capoen, Edouard | |
| dc.contributor.author | Pirovano, Caroline | |
| dc.contributor.author | Sandoval Rincón, Mónica Viviana | |
| dc.contributor.author | Cárdenas Velandia, Laura Carolina | |
| dc.contributor.author | Gauthier, Gilles Henri | |
| dc.contributor.author | Roussel, Pascal | |
| dc.contributor.cvlac | https://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0000939234 | |
| dc.contributor.cvlac | https://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0000051685 | |
| dc.contributor.cvlac | http://scienti.colciencias.gov.co:8081/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0001360806 | |
| dc.contributor.googlescholar | https://scholar.google.com/citations?user=s9hoJDcAAAAJ&hl=en | |
| dc.contributor.googlescholar | https://scholar.google.com/citations?user=53C-bPoAAAAJ&hl=fr | |
| dc.contributor.orcid | https://orcid.org/0000-0001-7216-0407 | |
| dc.contributor.orcid | https://orcid.org/0000-0001-7876-9985 | |
| dc.contributor.orcid | https://orcid.org/0000-0002-3479-6719 | |
| dc.contributor.orcid | https://orcid.org/0000-0002-8028-2030 | |
| dc.contributor.orcid | https://orcid.org/0000-0001-7243-7293 | |
| dc.date.accessioned | 2020-05-20T19:54:17Z | |
| dc.date.available | 2020-05-20T19:54:17Z | |
| dc.date.issued | 2019-03-06 | |
| dc.description.abstract | The electrochemical performance of La0.5Sr1.5MnO4±d (L5S15 M) as SOFC cathode was studied using Electrochemical Impedance Spectroscopy (EIS) measurements. The influence of the sintering temperature on the electrochemical performance was examined in air for Au/L5S15M/GDC/YSZ/GDC/L5S15 M/Au symmetrical cell. For the oxygen reduction reaction, the electron transfer between the electrode and oxygen, and the incorporation of oxygen ions into the electrode are the main controlling processes of oxygen reduction reaction for electrodes sintered at 1150 and 1200 C. Increasing the sintering temperature up to 1250 C increases the Sr diffusion through GDC interlayer, which leads to Sr accumulation at the GDC/YSZ interface with SrZrO3 formation and subsequent cell performance degradation. The lowest area specific resistance (ASR) values was obtained for the L5S15 M electrode sintered at 1150 C. | spa |
| dc.description.domain | http://unidadinvestigacion.usta.edu.co | spa |
| dc.format.mimetype | application/pdf | |
| dc.identifier.citation | Sandoval, M. V., Cárdenas, C., Capoen, E., Pirovano, C., Roussel, P., & Gauthier, G. H. (2019). Performance of La0.5Sr1.5MnO4±δ ruddlesden-popper manganite as electrode material for symmetrical solid oxide fuel cells. part A. the oxygen reduction reaction doi:https://doi.org/10.1016/j.electacta.2019.03.037 | spa |
| dc.identifier.doi | https://doi.org/10.1016/j.electacta.2019.03.037 | spa |
| dc.identifier.uri | http://hdl.handle.net/11634/23350 | |
| dc.publisher.branch | CRAI-USTA Bogotá | spa |
| dc.relation.references | S. Mekhilef, R. Saidur, A. Safari, Comparative study of different fuel cell technologies, Renew. Sustain. Energy Rev. 16 (2012) 981e989, https://doi.org/ 10.1016/j.rser.2011.09.020. | spa |
| dc.relation.references | N. Mahato, A. Banerjee, A. Gupta, S. Omar, K. Balani, Progress in material se- lection for solid oxide fuel cell technology: a review, Prog. Mater. Sci. 72 (2015) 141e337, https://doi.org/10.1016/j.pmatscN. Mahato, A. Banerjee, A. Gupta, S. Omar, K. Balani, Progress in material se- lection for solid oxide fuel cell technology: a review, Prog. Mater. Sci. 72 (2015) 141e337, https://doi.org/10.1016/j.pmatsci.2015.01.001.i.2015.01.001. | spa |
| dc.relation.references | C. Sun, R. Hui, J. Roller, Cathode materials for solid oxide fuel cells: a review, J. Solid State Electrochem. 14 (2010) 1125e1144, https://doi.org/10.1007/ s10008-009-0932-0. | spa |
| dc.relation.references | A. Mai, M. Becker, W. Assenmacher, F. Tietz, D. Hathiramani, E. Ivers-Tiffee, D. Stover, W. Mader, Time-dependent performance of mixed-conducting SOFC € cathodes, Solid State Ionics 177 (2006) 1965e1968, https://doi.org/10.1016/ j.ssi.2006.06.021. | spa |
| dc.relation.references | S.P. Jiang, A comparison of O2 reduction reactions on porous (La,Sr)MnO3 and (La,Sr)(Co,Fe)O3 electrodes, Solid State Ionics 146 (2002) 1e22. https://doi. org/10.1016/S0167-2738(01)00997-3. | spa |
| dc.relation.references | S.P. Jiang, A comparison of O2 reduction reactions on porous (La,Sr)MnO3 and (La,Sr)(Co,Fe)O3 electrodes, Solid State Ionics 146 (2002) 1e22. https://doi. org/10.1016/S0167-2738(01)00997-3. | spa |
| dc.relation.references | R. Sayers, M. Rieu, P. Lenormand, F. Ansart, J.A. Kilner, S.J. Skinner, Develop- ment of lanthanum nickelate as a cathode for use in intermediate temperature solid oxide fuel cells, Solid State Ionics 192 (2011) 531e534, https://doi.org/ 10.1016/j.ssi.2010.02.014. | spa |
| dc.relation.references | S. Liping, H. Lihua, Z. Hui, L. Qiang, C. Pijolat, La substituted Sr2MnO4 as a possible cathode material in SOFC, J. Power Sources 179 (2008) 96e100, https://doi.org/10.1016/j.jpowsour.2007.12.090. | spa |
| dc.relation.references | S. LiPing, L. Qiang, H. Li-Hua, Z. Hui, Z. Guo-Ying, L. Nan, J.-P. Viricelle, C. Pijolat, Synthesis and performance of Sr1.5LaxMnO4 as cathode materials for intermediate temperature solid oxide fuel cell, J. Power Sources 196 (2011) 5835e5839, https://doi.org/10.1016/j.jpowsour.2011.03.016. | spa |
| dc.relation.references | M.V. Sandoval, C. Pirovano, E. Capoen, R. Jooris, F. Porcher, P. Roussel, G.H. Gauthier, In-depth study of the Ruddlesden-Popper LaxSr2-xMnO4±d family as possible electrode materials for symmetrical SOFC, Int. J. Hydrog. Energy 42 (2017) 21930e21943, https://doi.org/10.1016/ j.ijhydene.2017.07.062. | spa |
| dc.relation.references | C. Munnings, S. Skinner, G. Amow, P. Whitfield, I. Davidson, Structure, stability and electrical properties of the La(2x)SrxMnO4±d solid solution series, Solid State Ionics 177 (2006) 1849e1853, https://doi.org/10.1016/j.ssi.2006.01.009. | spa |
| dc.relation.references | M.J. Jørgensen, M. Mogensen, Impedance of solid oxide fuel cell LSM/YSZ composite cathodes, J. Electrochem. Soc. 148 (2001) A433, https://doi.org/ 10.1149/1.1360203. | spa |
| dc.relation.references | J. Nielsen, J. Hjelm, Impedance of SOFC electrodes: a review and a compre- hensive case study on the impedance of LSM:YSZ cathodes, Electrochim. Acta 115 (2014) 31e45, https://doi.org/10.1016/j.electacta.2013.10.053. | spa |
| dc.relation.references | Q.-A. Huang, R. Hui, B. Wang, J. Zhang, A review of AC impedance modeling and validation in SOFC diagnosis, Electrochim. Acta 52 (2007) 8144e8164, https://doi.org/10.1016/j.electacta.2007.05.071. | spa |
| dc.relation.references | D. Johnson, ZView: a Software Program for IES Analysis, 2004, p. 8886, Version 3.4c. | spa |
| dc.relation.references | W.H. Kim, H.S. Song, J. Moon, W.H. Lee, Intermediate temperature solid oxide fuel cell using (La,Sr)(Co,Fe)O3-based cathodes, Solid State Ionics 177 (2006) 3211e3216, https://doi.org/10.1016/j.ssi.2006.07.049. | spa |
| dc.relation.references | J. Zhou, G. Chen, K. Wu, Y. Cheng, The performance of La0.6Sr1.4MnO4 layered perovskite electrode material for intermediate temperature symmetrical solid oxide fuel cells, J. Power Sources 270 (2014) 418e425, https://doi.org/ 10.1016/j.jpowsour.2014.06.163. | spa |
| dc.relation.references | A. Gondolini, E. Mercadelli, P. Pinasco, C. Zanelli, C. Melandri, A. Sanson, Alternative production route for supporting La0.8Sr0.2MnO3d-Ce0.8Gd0.2O2d (LSM-GDC), Int. J. Hydrog. Energy 37 (2012) 8572e8581. https://doi.org/10. 1016/j.ijhydene.2012.02.091. | spa |
| dc.relation.references | A.M. Yankin, O.M. Fedorova, I. a. Zvereva, S.G. Titova, V.F. Balakirev, Phase formation during synthesis of the LaSr2Mn2O7 compound, Glas, Phys. Chem. 32 (2006) 574e578, https://doi.org/10.1134/S1087659606050117. | spa |
| dc.relation.references | R.D. Shannon, Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides, Acta Cryst 32 (1976) 751e945. | spa |
| dc.relation.references | N. Hildenbrand, P. Nammensma, D.H. a Blank, H.J.M. Bouwmeester, B. a. Boukamp, Influence of configuration and microstructure on performance of La2NiO4þd intermediate-temperature solid oxide fuel cells cathodes, J. Power Sources 238 (2013) 442e453, https://doi.org/10.1016/ j.jpowsour.2013.03.192. | spa |
| dc.relation.references | E. Chinarro, J.R. Jurado, F.M. Figueiredo, J.R. Frade, Bulk and grain boundary conductivity of Ca0.97Ti1-xFexO3-d materials, Solid State Ionics 160 (2003) 161e168, https://doi.org/10.1016/S0167-2738(03)00151-6. | spa |
| dc.relation.references | E. Perry Murray, M.J. Sever, S.A. Barnett, Electrochemical performance of (La,Sr)(Co,Fe)O3-(Ce,Gd)O3 composite cathodes, Solid State Ionics 148 (2002) 27e34, https://doi.org/10.1016/S0167-2738(02)00102-9. | spa |
| dc.relation.references | A. Esquirol, N.P. Brandon, J.A. Kilner, M. Mogensen, Electrochemical charac- terization of La0.6Sr0.4Co0.2Fe0.8O3 cathodes for intermediate-temperature SOFCs, J. Electrochem. Soc. 151 (2004) A1847eA1855, https://doi.org/ 10.1149/1.1799391. | spa |
| dc.relation.references | K. Zhao, Y.-P. Wang, M. Chen, Q. Xu, B.-H. Kim, D.-P. Huang, Electrochemical evaluation of La2NiO4þd as a cathode material for intermediate temperature solid oxide fuel cells, Int. J. Hydrog. Energy 39 (2014) 7120e7130, https:// doi.org/10.1016/j.ijhydene.2014.02.106. | spa |
| dc.relation.references | J. Shen, G. Yang, Z. Zhang, W. Zhou, W. Wang, Z. Shao, Tuning layer-structured La0.6Sr1.4MnO4þd into a promising electrode for intermediate-temperature symmetrical solid oxide fuel cells through surface modification, J. Mater. Chem. A. 4 (2016) 10641e10649, https://doi.org/10.1039/C6TA02986H. | spa |
| dc.relation.references | J.C. Ruiz-Morales, J. Canales-Vazquez, J. Pe na-Martínez, D.M. L ~ opez, P. Nú nez, ~ On the simultaneous use of La0.75Sr0.25Cr0.5Mn0.5O3d as both anode and cathode material with improved microstructure in solid oxide fuel cells, Electrochim. Acta 52 (2006) 278e284, https://doi.org/10.1016/ j.electacta.2006.05.006. | spa |
| dc.relation.references | E. Schouler, Study of Oxide Solid Electrolyte Based Cells by the Complex Impedance Technique-Application to the Accurate Measurement of Conduc- tivity and to the Study of the Oxygen Electrode Reaction, Institut National Polytechnique de Grenoble (INPG)-France, 1979. | spa |
| dc.relation.references | S.B. Adler, J.A. Lane, B.C.H. Steele, Electrode kinetics of porous mixed- conducting oxygen electrodes, J. Electrochem. Soc. 143 (1996) 3554, https:// doi.org/10.1149/1.1837252. | spa |
| dc.relation.references | M. Liu, M. Liu, D. Ding, K. Blinn, X. Li, L. Nie, Enhanced performance of LSCF cathode through surface modification, Int. J. Hydrog. Energy 37 (2012) 8613e8620, https://doi.org/10.1016/j.ijhydene.2012.02.139. | spa |
| dc.relation.references | M. Liu, M. Liu, D. Ding, K. Blinn, X. Li, L. Nie, Enhanced performance of LSCF cathode through surface modification, Int. J. Hydrog. Energy 37 (2012) 8613e8620, https://doi.org/10.1016/j.ijhydene.2012.02.139. | spa |
| dc.relation.references | K. Zhao, Q. Xu, D.P. Huang, M. Chen, B.H. Kim, Electrochemical evaluation of La2NiO4þd-based composite electrodes screen-printed on Ce0.8Sm0.2O1.9 electrolyte, J. Solid State Electrochem. 16 (2012) 2797e2804, https://doi.org/ 10.1007/s10008-012-1702-y. | spa |
| dc.relation.references | S. Sunde, Calculations of impedance of composite anodes for solid oxide fuel cells, Electrochim. Acta 42 (1997) 2637e2648, https://doi.org/10.1016/s0013- 4686(96)00455-0. | spa |
| dc.relation.references | M.J. Escudero, A. Aguadero, J.A. Alonso, L. Daza, A kinetic study of oxygen reduction reaction on La2NiO4 cathodes by means of impedance spectroscopy, J. Electroanal. Chem. 611 (2007) 107e116, https://doi.org/10.1016/ j.jelechem.2007.08.006. | spa |
| dc.relation.references | Y.-P. Wang, Q. Xu, D.-P. Huang, K. Zhao, M. Chen, B.-H. Kim, Evaluation of La1.8Sr0.2NiO4þd as cathode for intermediate temperature solid oxide fuel cells, Int. J. Hydrog. Energy 41 (2016) 6476e6485, https://doi.org/10.1016/ j.ijhydene.2016.03.019. | spa |
| dc.relation.references | R. Kiebach, W. Zhang, M. Chen, K. Norrman, H.J. Wang, J.R. Bowen, R. Barfod, P.V. Hendriksen, W. Zhang, Stability of La0.6Sr0.4Co0.2Fe0.8O3/Ce0.9Gd0.1O2 cathodes during sintering and solid oxide fuel cell operation, J. Power Sources 283 (2015) 151e161, https://doi.org/10.1016/j.jpowsour.2015.02.064. | spa |
| dc.relation.references | F. Wang, M. Nishi, M.E. Brito, H. Kishimoto, K. Yamaji, H. Yokokawa, T. Horita, Sr and Zr diffusion in LSCF/10GDC/8YSZ triplets for solid oxide fuel cells (SOFCs), J. Power Sources 258 (2014) 281e289, https://doi.org/10.1016/ j.jpowsour.2014.02.046. | spa |
| dc.relation.references | M.Z. Khan, R.H. Song, S.B. Lee, J.W. Lee, T.H. Lim, S.J. Park, Effect of GDC interlayer on the degradation of solid oxide fuel cell cathode during acceler- ated current load cycling, Int. J. Hydrog. Energy 39 (2014) 20799e20805, https://doi.org/10.1016/j.ijhydene.2014.07.022. | spa |
| dc.relation.references | D. Szymczewska, J. Karczewski, A. Chrzan, P. Jasinski, CGO as a barrier layer between LSCF electrodes and YSZ electrolyte fabricated by spray pyrolysis for solid oxide fuel cells, Article in, Solid State Ionics (2016), https://doi.org/ 10.1016/j.ssi.2016.11.008. | spa |
| dc.relation.references | J.C. De Vero, K. Develos-Bagarinao, H. Kishimoto, T. Ishiyama, K. Yamaji, T. Horita, H. Yokokawa, Influence of La0.6Sr0.4Co0.2Fe0.8O3-d microstructure on GDC Interlayer stability and cation diffusion across the LSCF/GDC/YSZ In- terfaces, J. Electrochem. Soc. 163 (2016) F1463eF1470, https://doi.org/ 10.1149/2.0021614jes. | spa |
| dc.relation.references | F. Wang, M.E. Brito, K. Yamaji, D.H. Cho, M. Nishi, H. Kishimoto, T. Horita, H. Yokokawa, Effect of polarization on Sr and Zr diffusion behavior in LSCF/ GDC/YSZ system, Solid State Ionics 262 (2014) 454e459, https://doi.org/ 10.1016/j.ssi.2014.04.002. | spa |
| dc.relation.references | M. Morales, V. Miguel-Perez, A. Taranc on, A. Slodczyk, M. Torrell, B. Ballesteros, J.P. Ouweltjes, J.M. Bassat, D. Montinaro, A. Morata, Multi-scale analysis of the diffusion barrier layer of gadolinia-doped ceria in a solid oxide fuel cell operated in a stack for 3000 h, J. Power Sources 344 (2017) 141e151, https://doi.org/10.1016/j.jpowsour.2017.01.109. | spa |
| dc.relation.references | J.-T. Chou, Y. Inoue, T. Kawabata, J. Matsuda, S. Taniguchi, K. Sasaki, Mecha- nism of SrZrO3 formation at GDC/YSZ interface of SOFC cathode, J. Electrochem. Soc. 165 (11) (2018) F959eF965, https://doi.org/10.1149/ 2.0551811jes. | spa |
| dc.relation.references | F. Mauvy, C. Lalanne, J.-M. Bassat, J.-C. Grenier, H. Zhao, L. Huo, P. Stevens, Electrode properties of Ln2NiO4þd (Ln1⁄4La, Nd, Pr). AC impedance and DC polarization studies, J. Electrochem. Soc. 153 (2006) A1547eA1553, https:// doi.org/10.1149/1.2207059. | spa |
| dc.relation.references | L. Mogni, N. Grunbaum, F. Prado, A. Caneiro, Oxygen reduction reaction on ruddlesdenepopper phases studied by impedance spectroscopy, J. Electrochem. Soc. 158 (2011) B202eB207, https://doi.org/10.1149/ 1.3511770. | spa |
| dc.relation.references | K.V.G. Kutty, C.K. Mathews, T.N. Rao, U.V. Varadaraju, Oxide ion conductivity in some substituted rare earth pyrozirconates, Solid State Ionics 80 (1995) 99e110, https://doi.org/10.1016/0167-2738(95)00127-R. | spa |
| dc.relation.references | A. Mai, V.A.C. Haanappel, S. Uhlenbruck, F. Tietz, D. Stover, Ferrite-based pe- € rovskites as cathode materials for anode-supported solid oxide fuel cells: Part I. Variation of composition, Solid State Ionics 176 (2005) 1341e1350, https:// doi.org/10.1016/j.ssi.2005.03.009. | spa |
| dc.relation.references | H. Yokokawa, H. Tu, B. Iwanschitz, A. Mai, Fundamental mechanisms limiting solid oxide fuel cell durability, J. Power Sources 182 (2008) 400e412, https:// doi.org/10.1016/j.jpowsour.2008.02.016. | spa |
| dc.relation.references | C. Endler-Schuck, J. Joos, C. Niedrig, A. Weber, E. Ivers-Tiffee, The chemical oxygen surface exchange and bulk diffusion coefficient determined by impedance spectroscopy of porous La0.58Sr0.4Co0.2Fe0.8O3-d (LSCF) cathodes, Solid State Ionics 269 (2015) 67e79, https://doi.org/10.1016/j.ssi.2014.11.018. | spa |
| dc.relation.references | J.D. Kim, G.D. Kim, J.W. Moon, Y. il Park, W.H. Lee, K. Kobayashi, M. Nagai, C.E. Kim, Characterization of LSM-YSZ composite electrode by ac impedance spectroscopy, Solid State Ionics 143 (2001) 379e389, https://doi.org/10.1016/ S0167-2738(01)00877-3. | spa |
| dc.relation.references | S.P. Yoon, S.W. Nam, S.G. Kim, S.A. Hong, S.H. Hyun, Characteristics of cathodic polarization at Pt/YSZ interface without the effect of electrode microstructure, J. Power Sources 115 (2003) 27e34, https://doi.org/10.1016/S0378-7753(02) 00720-6. | spa |
| dc.relation.references | D. Chen, R. Ran, K. Zhang, J. Wang, Z. Shao, Intermediate-temperature elec- trochemical performance of a polycrystalline PrBaCo2O5þd cathode on samarium-doped ceria electrolyte, J. Power Sources 188 (2009) 96e105, https://doi.org/10.1016/j.jpowsour.2008.11.045. | spa |
| dc.relation.references | T. Kenjo, M. Nishiya, LaMnO3 air cathodes containing ZrO2 electrolyte for high temperature solid oxide fuel cells, Solid State Ionics 57 (1992) 295e302, https://doi.org/10.1016/0167-2738(92)90161-H. | spa |
| dc.relation.references | G.C. Kostogloudis, G. Tsiniarakis, C. Ftikos, Chemical reactivity of perovskite oxide SOFC cathodes and yttria stabilized zirconia, Solid State Ionics 135 (2000) 529e535, https://doi.org/10.1016/S0167-2738(00)00433-1. | spa |
| dc.relation.references | A. Mitterdorfer, L.J. Gauckler, La2Zr2O7 formation and oxygen reduction ki- netics of the La0.85Sr0.15MnyO3, O2(g)jYSZ system, Solid State Ionics 111 (1998) 185e218, https://doi.org/10.1016/S0167-2738(98)00195-7. | spa |
| dc.relation.references | M.C. Brant, L. Dessemond, Electrical degradation of LSM-YSZ interfaces, Solid State Ionics 138 (2000) 1e17, https://doi.org/10.1016/S0167-2738(00)00769- 4. | spa |
| dc.relation.references | A. Mai, V.A.C. Haanappel, F. Tietz, D. Stover, Ferrite-based perovskites as € cathode materials for anode-supported solid oxide fuel cells. Part II. Influence of the CGO interlayer, Solid State Ionics 177 (2006) 2103e2107, https:// doi.org/10.1016/j.ssi.2005.12.010. | spa |
| dc.relation.references | G. Constantin, C. Rossignol, P. Briois, A. Billard, L. Dessemond, E. Djurado, Efficiency of a dense thin CGO buffer layer for solid oxide fuel cell operating at intermediate temperature, Solid State Ionics 249e250 (2013) 98e104, https:// doi.org/10.1016/j.ssi.2013.07.004. | spa |
| dc.relation.references | H.G. Jung, Y.K. Sun, H.Y. Jung, J.S. Park, H.R. Kim, G.H. Kim, H.W. Lee, J.H. Lee, Investigation of anode-supported SOFC with cobalt-containing cathode and GDC interlayer, Solid State Ionics 179 (2008) 1535e1539, https://doi.org/ 10.1016/j.ssi.2008.01.063. | spa |
| dc.relation.references | M.Z. Khan, M.T. Mehran, R.H. Song, J.W. Lee, S.B. Lee, T.H. Lim, S.J. Park, Effect of GDC interlayer thickness on durability of solid oxide fuel cell cathode, Ceram. Int. 42 (2015) 6978e6984, https://doi.org/10.1016/ j.ceramint.2016.01.085. | spa |
| dc.relation.references | A. Endo, H. Fukunaga, C. Wen, K. Yamada, Cathodic reaction mechanism of dense La0.6Sr0.4CoO3 and La0.81Sr0.09MnO3 electrodes for solid oxide fuel cells, Solid State Ionics 135 (2000) 353e358, https://doi.org/10.1016/S0167- 2738(00)00466-5. | spa |
| dc.relation.references | M.J. Verkerk, B.J. Middelhuis, A.J. Burggraaf, Effect of grain boundaries on the conductivity of high-purity ZrO2-Y2O3 ceramics, Solid State Ionics 6 (1982) 159e170, https://doi.org/10.1016/0167-2738(82)90083-2. | spa |
| dc.relation.references | G. Christie, F.P. Van Berkel, Microstructure-ionic conductivity relationships in ceria-gadolinia electrolytes, Solid State Ionics 83 (1996) 17e27, https:// doi.org/10.1016/0167-2738(95)00155-7. | spa |
| dc.relation.references | M. Mogensen, N.M. Sammes, G.A. Tompsett, Physical, chemical and electro- chemical properties of pure and doped ceria, Solid State Ionics 129 (2000) 63e94. https://doi.org/10.1016/S0167-2738(99)00318-5. | spa |
| dc.relation.references | A. Hagen, Y.L. Liu, R. Barfod, P.V. Hendriksen, Assessment of the cathode contribution to the degradation of anode-supported solid oxide fuel fells, J. Electrochem. Soc. 155 (2008) B1047eB1052, https://doi.org/10.1149/ 1.2960938. | spa |
| dc.relation.references | L. Barelli, E. Barluzzi, G. Bidini, Diagnosis methodology and technique for solid oxide fuel cells: a review, Int. J. Hydrog. Energy 38 (2013) 5060e5074, https:// doi.org/10.1016/j.ijhydene.2013.02.024. | spa |
| dc.relation.references | J. Nielsen, M. Mogensen, SOFC LSM:YSZ cathode degradation induced by moisture: an impedance spectroscopy study, Solid State Ionics 189 (2011) 74e81, https://doi.org/10.1016/j.ssi.2011.02.019. | spa |
| dc.relation.references | F. Bidrawn, R. Küngas, J.M. Vohs, R.J. Gorte, Modeling impedance response of SOFC cathodes prepared by infiltration, J. Electrochem. Soc. 158 (2011) B514eB525, https://doi.org/10.1149/1.3565174. | spa |
| dc.relation.references | M. Liu, Z. Liu, M. Liu, L. Yang, LSM-infiltrated LSCF cathodes for solid oxide fuel cells, J. Energy Chem. 22 (2013) 555e559, https://doi.org/10.1016/S2095- 4956(13)60072-8. | spa |
| dc.rights | Atribución-NoComercial-SinDerivadas 2.5 Colombia | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/2.5/co/ | |
| dc.subject.keyword | Symmetrical SOFC | spa |
| dc.subject.keyword | Ruddlesden-Popper | spa |
| dc.subject.keyword | Manganite | spa |
| dc.subject.keyword | Electrochemical impedance spectroscopy | spa |
| dc.subject.keyword | Oxygen reduction reaction | spa |
| dc.subject.lemb | Manganita | spa |
| dc.subject.lemb | Espectroscopía de impedancia | spa |
| dc.subject.proposal | SOFC simétrico | spa |
| dc.subject.proposal | Espectroscopía de impedancia electroquímica | spa |
| dc.subject.proposal | Reacción de reducción de oxígeno | spa |
| dc.title | Performance of La0.5Sr1.5MnO4±d Ruddlesden-Popper manganite as electrode material for symmetrical solid oxide fuel cells. Part A. The oxygen reduction reaction | spa |
| dc.type.category | Apropiación Social y Circulación del Conocimiento: Edición de revista o libro de divulgación científica | spa |